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Physical and chemical properties of zinc sulfide ZnS powder

2022-06-14 09:27:00  News

Overview of Zinc Sulfide ZnS

Zinc sulfide is a white to off-white or light yellow powder, which becomes darker when exposed to light, stable in dry air, and gradually oxidized to zinc sulfate when stored for a long time in humid air or containing water. Soluble in dilute inorganic acid, soluble in alkali, insoluble in water. Relative density 3.98 (alpha type), (d25) 4.102 (beta type). irritating.

ZnS exists in two main crystal types, and this duality is often a prominent example of polymorphism. In each form, the coordination geometry of Zn and S is tetrahedral. The more stable cubic form is also known as sphalerite. The hexagonal form is known as the mineral wurtzite, although it can also be produced synthetically. The transformation from sphalerite to wurtzite occurs at approximately 1020°C. Sifang is also known as a very rare mineral called Lithium Manganese Ore with the molecular formula (Zn,Hg)S.

Physical and chemical properties of zinc sulfide ZnS powder

The chemical bond between Zn and S of zinc sulfide tends to be a covalent bond. The crystal has three different configurations: low temperature type, that is, sphalerite structure, abundant in nature, colorless cubic crystal, Zn, S coordination number is 4, relative density is 4.10. 1020 ℃ High temperature type; high temperature type, namely wurtzite structure, colorless hexagonal crystal, Zn, S coordination number of 4, relative density 3.98, melting point about 1700 ℃. High temperature stable structure of zinc sulfide; high pressure type, namely chloride In the sodium structure, the coordination number of Zn and S is 6, and the relative density is 5.21. There is also a water-based compound, ZnS·H2O, which is a white powder with a relative density of 3.98 and a melting point of 1049 °C. Zinc sulfide is insoluble in water and dilute alkali, insoluble in acetic acid, but soluble in low-concentration strong acids such as hydrochloric acid, releasing hydrogen sulfide. The solubility product of zinc sulfide is similar to the K1·K2 value of hydrosulfuric acid, so the following equilibrium exists in dilute acid:

Zn2+H2S=2H+ZnS

It can be seen that in the strong acid zinc salt solution, the hydrogen sulfide gas cannot obtain zinc sulfide precipitation. Passing hydrogen sulfide gas into the zinc salt solution can get zinc sulfide precipitation, but the precipitation is not complete. Using ammonium sulfide solution as precipitating agent, the zinc ions in the zinc salt solution can be completely precipitated into zinc sulfide. Since the ammonium sulfide solution is alkaline, the acidity of the system can be reduced. In industry, the above method should be used to isolate the air. White zinc sulfide darkens when exposed to light, and is easily oxidized to zinc sulfate in the air. Zinc sulfide can be used alone as a white paint pigment or in combination with zinc oxide. Pure zinc sulfide does not emit light. If a trace amount of manganese, copper, and silver are added to the zinc sulfide crystal as an activator, it can emit different colors of fluorescence after being illuminated, called phosphor powder, which is used to make fluorescent screens and luminous paints. Zinc sulfide is also used in leather, enamel, rubber, dye and other industries.

Zinc sulfide is corrosive and toxic. It can irritate the skin. Operators should wear work clothes and protective equipment. The workshop should be well ventilated.

Physical and chemical properties of zinc sulfide ZnS powder

Application of zinc sulfide ZnS

Zinc sulfide is often made from scrap and used for other purposes. Typical sources include smelters, slags and pickling liquors. It is also a by-product of ammonia synthesis from methane, where zinc oxide is used to remove hydrogen sulfide impurities from natural gas.

High-purity crystalline zinc sulfide powder is an important basic material, which is widely used in civil, military, aerospace and other high-tech fields. It is also an extremely important window material for medium and long-wave far-infrared precision guidance and far-infrared imaging, especially in frontier technology fields such as national defense and military. The applications of zinc sulfide are as follows: Luminescent material.

Zinc sulfide, with a small amount of a suitable activator, is highly phosphorescent and is currently used in a variety of applications from cathode ray tubes to X-ray screens to glow in dark products. When silver is used as the activator, the resulting color is bright blue with a maximum wavelength of 450 nm. The use of manganese produces a red-orange color around 590 nm. Copper glows for a long time and has the deep green glow we are familiar with. Copper-doped zinc sulfide ("ZnS+Cu") is also used in electroluminescent panels. It also exhibits phosphorescence due to impurities in blue or ultraviolet light.

Zinc sulfide ZnS price

The price of zinc sulfide and zinc sulfide products will vary randomly due to factors such as production costs, transportation costs, international conditions, exchange rates, and market supply and demand of zinc sulfide and zinc sulfide products. Tanki New Materials Co., Ltd. aims to help industries and chemical wholesalers find high-quality, low-cost nanomaterials and chemicals by providing a full range of customized services. If you are looking for Zinc Sulfide ZnS products, please feel free to send an inquiry to get the latest Zinc Sulfide ZnS product prices.

Suppliers of Zinc Sulfide ZnS

As a global supplier of zinc sulfide ZnS products, Tanki New Materials Co., Ltd. has extensive experience in the performance, application and cost-effective manufacturing of advanced engineering materials. The company has successfully developed a series of powder materials (molybdenum disulfide, tungsten sulfide, bismuth sulfide, etc.) high-purity targets, functional ceramics and structural devices, and provides OEM services.

Technical Parameter of Zinc Sulfide ZnS Powder :
Particle sizeZnSWaterFe,mg/kgCu,mg/kgPb, mg/kgNi, mg/kgCd,mg/kgMn, mg/kgPH
3-5μm99.99%≤0.8%<10<0.3<2.0<5.0<0.3<0.26.0-7.0


Zinc Sulfide Properties
Other NamesZnS powder, zinc sulphide, zinc sulfide phosphor
CAS No.1314-98-3
Compound FormulaZnS
Molecular Weight97.45
AppearanceWhite to off-white Powder
Melting Point1830 °C
Boiling PointN/A
Density4.1 g/cm3
Solubility in H2ON/A
Poisson's Ratio0.28
Specific Heat520 J/kg-K
Thermal Conductivity 27 W/m-K
Thermal Expansion6.5 µm/m-K
Young's Modulus75 GPa
Zinc Sulfide Health & Safety Information
Signal WordN/A
Hazard StatementsN/A
Flash PointN/A
Hazard CodesN/A
Risk CodesN/A
Safety StatementsN/A
RTECS NumberZH5400000
Transport InformationNONH for all modes of transport
WGK Germanynwg



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